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- W2050187410 abstract "Abstract A series of new para-substituted (E)-(N)-styrylcarbazoles, i.e., eight (E)-9-[2-(aryl)ethenyl]-9H-carbazoles (5–12) and 1,4-bis[(E)-2-(9H-carbazol-9-yl)vinyl]benzene (13), have been synthesized in high yield and stereoselectively by a sequential silylative coupling–Hiyama coupling reaction, i.e., coupling of commercially available 9-vinylcarbazole with vinyltriethoxysilane or divinyltetramethyldisiloxane in the presence of [RuHCl(CO)(PCy3)2] (I), followed by Pd (II) catalyzed cross-coupling with para-substituted iodobenzenes. The tandem procedure has facilitated the synthesis of 13. X-ray structures of the intermediate silylvinylcarbazole (4), as well as products 12 and 13 have been obtained." @default.
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- W2050187410 date "2007-01-01" @default.
- W2050187410 modified "2023-10-03" @default.
- W2050187410 title "Highly stereoselective synthesis of para-substituted (E)-N-styrylcarbazoles via sequential silylative coupling–Hiyama coupling reaction" @default.
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- W2050187410 doi "https://doi.org/10.1016/j.tet.2006.11.065" @default.
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