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- W2050225087 abstract "Abstract We address our full attention to the various useful capabilities of the Raman scattering technique for characterizing high- T c superconducting oxides. The powerful aspect of Raman spectroscopy is demonstrated with regard to detection of traces of impurities as compared with the conventional X-ray diffraction technique. Oxygen disordering within CuO chains in Co-doped Y123 type materials is sensitively detected by the Raman scattering technique, the degree of which is proportional to the intensity of the disorder induced Raman mode above 550 cm −1 . The phonon Raman spectra of (Pb 2 Cu)Sr 2 Y 1− x Ca x Cu 2 O 8+ d , (Pb 2 Cu)Sr 0.9 La 1.1 CuO 6+ d and (Pb 0.5 Cu 0.5 )Sr 2 YCu 2 O 7+ d are investigated and phonon assignments compatible with the layer stacking sequences found in these Pb-based cuprates are proposed. Raman scattering can also be used as a means to detect insulator-to-metal transitions in various high- T c cuprates, an example of which is demonstrated for (Pb 2 Cu)Sr 2 Y 1− x Ca x Cu 2 O 8+ d ; the intensity for the B 1 g O Cu mode abruptly drops across the insulator-to-metal transition as a result of the increased metallic screening in the hole-introduced samples." @default.
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- W2050225087 title "Raman spectroscopy as a unique tool for characterizing high-Tc superconducting oxides" @default.
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- W2050225087 doi "https://doi.org/10.1016/s0921-4534(00)00217-3" @default.
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