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• W2050238049 abstract "Abstract CsNSO 2 reacts with fluoro complexes, trans -[M(CO)F(PPh 3 ) 2 ] (MRh, Ir) to give sulfonylnitrido complexes, trans -[M(CO)(NSO 2 )(PPh 3 ) 2 ] which react with triphenylphosphine to afford thionitro complexes, trans -[M(CO)(NSO)(PPh 3 ) 2 ]. The thionitro complexes are also prepared by the reaction of CsNSO 2 with hydrido complexes, [MH(CO)(PPh 3 ) 2 ]. Reaction of CsNSO 2 with [RuH 2 (CO)(PPh 3 ) 2 ] yields [Ru(CO)(NSO 2 ) 2 (PPh 3 ) 2 ]. The sulfonylnitrido complexes of the type Cs 2 [M′(NS)(NSO 2 ) 2 Cl 3 ] (M′Ru, Os) are prepared by the reaction of CsNSO 2 and [M′(NS)Cl 3 ]. The reactions of heptasulfurimide with [RhCl(PPh 3 ) 3 ] and [Rh(CO)Cl(PPh 3 ) 3 ] afford disulfidothinitrato complexes [Rh(S 3 N)(PPh 3 ) 2 ] and [Rh(CO)(S 3 N)(PPh 3 ) 2 ], respectively. CNDO/2 molecular orbital calculations have been performed on the model systems trans -[Rh(CO)L(PH 3 ) 2 ] (LNSO, SH, Cl) in order to investigate the nature and energetics of the interaction between rhodium and NSO, SH, Cl ligands. The computed trends for RhX, RhC and CO bond strengths, as measured by Wiberg indices and charge distributions, suggest that the strength of the coordination bond RhL increases in the order [RhNSO] 3 ) 2 ] 3 ) 2 ] 3 ) 2 ]. The trend in CO bond strength is [Rh(CO)Cl(PH 3 ) 2 ]>[Rh(CO)(NSO)-(PH 3 ) 2 ]>[Rh(CO)(SH)(PH 3 ) 2 ]. The NSO group is the worst π-acceptor amongst the three ligands." @default.
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• W2050238049 date "1991-04-01" @default.
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• W2050238049 title "Coordination chemistry of NSO−, NSO2− and S3N− ligands: comparison of electronic structure of RhNSO, RhSH and RhCl complexes" @default.
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• W2050238049 doi "https://doi.org/10.1016/s0020-1693(00)90151-8" @default.
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