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- W2050252204 abstract "The electron paramagnetic resonance spectrum of Gd3+ in EuCl3.6H2O, with 1/250 dilution of Gd/Eu ions, has been studied with an X-band spectrometer at 295 K, 79 K and 1.60 K. The low temperature data was used to determine the signs of parameters. In particular, the following values for the g-tensor and the zero-field splitting parameter b20 were obtained: at 295 K, gzz = 1.992 ± 0.005, gzz = 2.000 ± 0.005, gyy = 1.994 ± 0.005, b20 = 1.876 ± 0.01 5 GHz; at 79 K gzz = 1.992 ± 0.005, gxx = 1.990 ± 0.005, b20 = 1.950 ± 0.015 GHz; at 1.60 K gzz = 1.99 ± 0.01, gxx = 1.99 ± 0.01, b20 = 1.95 ± 0.03 GHz. The values of other parameters were also determined. From the angular variation of spectrum in the ZX plane the angle α0, which the Z axis makes with the a vector of the unit cell, was determined to be 64.00 ± 0.25°. Estimates were also made of the extent of admixture of the excited 6P72 state with the ground state 8S72." @default.
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- W2050252204 date "1976-06-01" @default.
- W2050252204 modified "2023-09-27" @default.
- W2050252204 title "Electron paramagnetic resonance of Gd3+ in EuCl3.6H2O" @default.
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- W2050252204 doi "https://doi.org/10.1016/0378-4363(76)90218-7" @default.
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