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- W2050337265 abstract "During the mass-spectrometric investigation of the Na-O-P system in molybdenum crucibles, in addition to the gaseous molybdenum oxides, MoO, MoO2 and MoO3, gaseous sodium molybdates (V and VI) and molybdite (IV) have been identified and their stabilities determined. From the enthalpy changes for the isomolecular reactions involving the gaseous species NaPO2, NaPO3, NaMoO3, Na2MoO3, Na2MoO4, MoO2 and MoO3, the standard heats of formation, and atomization energies at 298 K in kcal moP−1 have been derived as −128.1 ± 8, 489.8 ± 8 (NaMoO3); −175.0 ± 14, 562.3 ± 14 (Na2MoO3); −257.3 ± 12, 704.4 ± 12 (Na2MoO4). By combining the enthalpy change of the pressure-independent reaction involving the gaseous molybdenum oxides MoO, MoO2, and MoO3, with the selected values of JANAF for standard heats of formation of MoO2 (g) and MoO3(g), revised values have been obtained for the dissociation energy (145.1 ± 8 kcalmol−1) and standard heat of formation (71.8 ± 8 kcalmol−1) of MoO(g) at 298 K. By comparing the stability trends in condensed and gaseous hydrogen and alkali metal tungstates, molybdates, chromâtes and sulphates, the atomization energies of the gaseous compounds of alkali metals at 298 K have been recommended as 767 ± 12 (tungstates), 708 ± 12 (molybdates); 620 ±12 (chromates) and 597 ± 6 (sulphates) kcal mol−1." @default.
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- W2050337265 date "1975-08-01" @default.
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- W2050337265 title "Mass spectrometric determination of the thermodynamic stabilities of gaseous molybdenum oxides and sodium molybdates and predicted stabilities of gaseous group ia tungstates, molybdates, chromates and sulfates" @default.
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- W2050337265 doi "https://doi.org/10.1016/0022-5088(75)90025-9" @default.
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