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- W2050384518 abstract "Infrared spectra of solutions of M 2 [V 2 O 2 (O 2 ) 4 H 2 O] . aq (M = N(CH 3 ) 4 , N(C 4 H 9 ) 4 ) in heavy water and acetonitrile indicate that in concentrated solutions ( c >= 0.5 mol dm -3 ) the asymmetric structure of the [V 2 O 2 (O 2 ) 4 H 2 O] 2- anion remains preserved for some time. Electronic spectra suggest that in more dilute solutions ( c = 10 -3 -10 -4 mol dm -3 ) of the M 2 [V 2 O 2 (O 2 ) 4 H 2 O] . aq complexes in water and acetonitrile the dinuclear ion decomposes faster to [VO(O 2 ) 2 H 2 O] - , followed by a relatively slow liberation of the peroxidic oxygen and formation of vanadate ions. The dinuclear complex is more stable in dilute chloroform solutions. The 51 V NMR spectrum of an aqueous solution of [N(CH 3 ) 4 ] 2 [V 2 O 2 (O 2 ) 4 H 2 O] (c = 1.3 mol dm -3 ) taken after a partial decomposition suggests the simultaneous presence of [V 2 O 2 (O 2 ) 4 H 2 O] 2- , [VO(O 2 ) 2 H 2 O] - , ( V n O 3 n ) n - ( n = 4, 5, 6), [H m V 10 O 28 ] (6- m )- , and other unidentified species." @default.
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- W2050384518 date "1996-01-01" @default.
- W2050384518 modified "2023-10-10" @default.
- W2050384518 title "Spectral Investigation of Stability of the Peroxo Complexes M2[V2O2(O2)4H2O] . aq (M = N(CH3)4, N(C4H9)4) in Solutions" @default.
- W2050384518 doi "https://doi.org/10.1135/cccc19960868" @default.
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