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- W2050465107 abstract "The phase transformations of NiMn films were investigated using differential scanning calorimetry (DSC), transmission electron microscopy (TEM), and x-ray diffraction (XRD). The sputter deposited NiMn thin films onto room temperature substrates were observed to possess a metastable, chemically disordered, mixture of amorphous and face centered cubic (fcc) phases. DSC measurements revealed four exothermic peaks. TEM studies determined that the DSC peaks were associated with the oxidation of the Mn, two phase transformation reactions (amorphous to fcc and fcc to L10) and grain growth of L10 phase. Using DSC, the enthalpy (activation energy) for amorphous to fcc and fcc to L10 transformations has been measured yielding values of −1.4, −4.7kJ∕mol (121±25 and 140±25kJ∕mol), respectively. The enthalpy of grain growth has been determined as −1.1kJ∕mol. The kinetics of the reaction was simulated using the Johnson–Mehl–Avrami analysis, where the necessary parameters were determined by the Kissinger method on DSC data and also from XRD data of isothermal annealed samples." @default.
- W2050465107 created "2016-06-24" @default.
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- W2050465107 date "2005-03-04" @default.
- W2050465107 modified "2023-09-26" @default.
- W2050465107 title "Kinetic study on the phase transformations in sputter deposited NiMn thin films" @default.
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- W2050465107 doi "https://doi.org/10.1063/1.1862760" @default.
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