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- W2050470916 abstract "We report the first measurements of delayed ionization of the metallofullerene La@C82. When highly excited in laser desorption, La@C82 was found to ionize over several microseconds. The rate of delayed ionization of La@C82 was compared to C60 under the same extraction conditions, and found to be significantly different. A theoretical model was used for the fitting of the ion signal of the two fullerenes. The metallofullerene results can be fitted well over a time window <30 μs and are consistent with a low ionization potential (6.3 eV) and a high radiative cooling rate. The C60 data cannot be fitted over the same time window, indicative of an additional time-dependent competing decay channel." @default.
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- W2050470916 date "2002-11-12" @default.
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- W2050470916 title "Investigations into the fragmentation and ionization of highly excited La@C82" @default.
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- W2050470916 doi "https://doi.org/10.1063/1.1513465" @default.
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