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- W2050484548 abstract "Infrared studies of one-dimensional conductors of the cation-deficient type M1.75[Pt(CN)4]⋅1.5H2O, where M=K, Rb, or Cs are reported. Results are compared with those previously reported for the anion-deficient conductors as well as between the starting materials, unoxidized K2[Pt+2(CN)4]⋅3H2O and fully oxidized K2[Pt+4(CN)4Br2]. It is observed that some of the infrared-active vibrations are sensitive to the oxidation state of Pt. The trends are explained in terms of an increase in metal–CN π-back bonding, and a decrease in the metal–carbon sigma bonding. Spectral data are included for the organic guanidinium tetracyanoplatinate 1-D conductor." @default.
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- W2050484548 title "Infrared studies of one-dimensional conductors of the cation-deficient type: M1.75[Pt(CN)4]⋅1.5H2O where <i>M</i>=K, Rb, or Cs" @default.
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- W2050484548 doi "https://doi.org/10.1063/1.434855" @default.
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