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• W2050486510 abstract "Grafting of maleic anhydride (MAH) onto metallocene based polyethylene–octene elastomer (POE) was studied in this article. By the results of Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, and differential scanning calorimetry (DSC), it was confirmed that POE was grafted with MAH but the crosslinking reaction was accompanied by the predominant graft reaction due to a competition of POE macro-radical and excited MAH. Effects of various parameters such as monomer loading, initiator loading, and reaction time on grafting percentage and gel yield were also investigated. It was also found that the grafting percentage and the gel yield, at equilibrium, were both higher for POE containing lower degree of comonomer content. From the result of DSC characterization, it was shown that the change of crystallinity is slight for POE-g-MAH copolymer when the gel was removed from the copolymer. So one thought that the effect of gel formation on the properties of POE-g-MAH can be n..." @default.
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• W2050486510 date "2002-10-09" @default.
• W2050486510 modified "2023-09-24" @default.
• W2050486510 title "STUDY ON THE GRAFT REACTION OF MALEIC ANHYDRIDE ONTO METALLOCENE-BASED POLYETHYLENE–OCTENE ELASTOMER" @default.
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• W2050486510 doi "https://doi.org/10.1081/ppt-120006439" @default.
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