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- W2050556743 abstract "A scalable and cost-effective synthesis of d- and l-α-methylcysteine is described. A key step is d-selective cyclization of N-carbamoyl S-tert-butyl-d,l-α-methylcysteine catalyzed by hydantoinase. d-5-tert-Butylthiomethyl-5-methylhydantoin and N-carbamoyl S-tert-butyl-l-α-methylcysteine were obtained with excellent yield and optical purity, and these compounds were easily separated by filtration. After hydrolysis and cleavage of the tert-butyl group, d- and l-α-methylcysteine hydrochloride were obtained." @default.
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- W2050556743 date "2007-05-01" @default.
- W2050556743 modified "2023-09-25" @default.
- W2050556743 title "Enantioselective synthesis of d- and l-α-methylcysteine with hydantoinase" @default.
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- W2050556743 doi "https://doi.org/10.1016/j.tetlet.2007.03.040" @default.
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