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• W2050584428 startingPage "17096" @default.
• W2050584428 abstract "Vapor phase OH-stretching overtone spectra of ethylene glycol were recorded to investigate weak intramolecular hydrogen bonding. The spectra were recorded with conventional absorption spectroscopy and laser photoacoustic spectroscopy in the first to fourth OH-stretching overtone regions. The room-temperature spectra are dominated by two conformers that show weak intramolecular hydrogen bonding. A less abundant third conformer, with no sign of hydrogen bonding, is also observed. Vapor phase spectra of the ethylene-d(4) glycol isotopomer were also recorded and used to identify an interfering resonance between CH-stretching and OH-stretching states in the fourth overtone. Anharmonic oscillator local mode calculations of the OH-stretching transitions have provided an accurate simulation of the observed spectra. The local mode parameters were calculated with coupled cluster ab initio methods. The calculations facilitate assignment of the different conformers in the spectra and illustrate the effect of the intramolecular hydrogen bonding." @default.
• W2050584428 created "2016-06-24" @default.
• W2050584428 creator A5015994832 @default.
• W2050584428 creator A5023289690 @default.
• W2050584428 creator A5091638129 @default.
• W2050584428 date "2005-11-11" @default.
• W2050584428 modified "2023-09-30" @default.
• W2050584428 title "Weak Intramolecular Interactions in Ethylene Glycol Identified by Vapor Phase OH−Stretching Overtone Spectroscopy" @default.
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• W2050584428 doi "https://doi.org/10.1021/ja055827d" @default.
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• W2050584428 hasPublicationYear "2005" @default.
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