Matches in SemOpenAlex for { <https://semopenalex.org/work/W2050584612> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2050584612 endingPage "241" @default.
- W2050584612 startingPage "233" @default.
- W2050584612 abstract "The t-butanoyl substituent of η6-benzene-η5-t-butanoylcyclopentadienyliron(II) hexafluorophosphate rearranges to a 3-methylbutan-2-oyl group under the influence of electrophilic catalysts such as AlCl3 or CF3SO3H. This typical rearrangement of α-branched ketones has been studied in several acids, and the rates are compared to those for the analogous rearrangement of the uncomplexed t-butyl phenyl ketones. The presence of the C6H6Fe+ group markedly increases the rate of reaction. η6-t-Butanoylbenzene-η5-cyclopentadienyliron(II) hexafluorophosphate was also found to undergo a similar rearrangement, but there was a major competing reaction involving loss of the t-butanoyl substituent. The presence of the (arene)Fe+(cp) group causes a 104–105 fold increase in the rate of the rearrangement." @default.
- W2050584612 created "2016-06-24" @default.
- W2050584612 creator A5044762557 @default.
- W2050584612 creator A5057252909 @default.
- W2050584612 date "1986-12-01" @default.
- W2050584612 modified "2023-09-23" @default.
- W2050584612 title "Acid-catalysed ketone rearrangements of t-butanoyl substituted η6-arene-η5-cyclopentadienyliron(II) cations" @default.
- W2050584612 cites W1579049421 @default.
- W2050584612 cites W1583455080 @default.
- W2050584612 cites W1965002475 @default.
- W2050584612 cites W1965920531 @default.
- W2050584612 cites W1970556736 @default.
- W2050584612 cites W1990793692 @default.
- W2050584612 cites W2009521071 @default.
- W2050584612 doi "https://doi.org/10.1016/0022-328x(86)80525-3" @default.
- W2050584612 hasPublicationYear "1986" @default.
- W2050584612 type Work @default.
- W2050584612 sameAs 2050584612 @default.
- W2050584612 citedByCount "5" @default.
- W2050584612 crossrefType "journal-article" @default.
- W2050584612 hasAuthorship W2050584612A5044762557 @default.
- W2050584612 hasAuthorship W2050584612A5057252909 @default.
- W2050584612 hasConcept C154881586 @default.
- W2050584612 hasConcept C155647269 @default.
- W2050584612 hasConcept C161790260 @default.
- W2050584612 hasConcept C178790620 @default.
- W2050584612 hasConcept C185592680 @default.
- W2050584612 hasConcept C2776138744 @default.
- W2050584612 hasConcept C2777598222 @default.
- W2050584612 hasConcept C2777691172 @default.
- W2050584612 hasConcept C2777738585 @default.
- W2050584612 hasConcept C2778689049 @default.
- W2050584612 hasConcept C50027330 @default.
- W2050584612 hasConcept C71240020 @default.
- W2050584612 hasConceptScore W2050584612C154881586 @default.
- W2050584612 hasConceptScore W2050584612C155647269 @default.
- W2050584612 hasConceptScore W2050584612C161790260 @default.
- W2050584612 hasConceptScore W2050584612C178790620 @default.
- W2050584612 hasConceptScore W2050584612C185592680 @default.
- W2050584612 hasConceptScore W2050584612C2776138744 @default.
- W2050584612 hasConceptScore W2050584612C2777598222 @default.
- W2050584612 hasConceptScore W2050584612C2777691172 @default.
- W2050584612 hasConceptScore W2050584612C2777738585 @default.
- W2050584612 hasConceptScore W2050584612C2778689049 @default.
- W2050584612 hasConceptScore W2050584612C50027330 @default.
- W2050584612 hasConceptScore W2050584612C71240020 @default.
- W2050584612 hasIssue "2" @default.
- W2050584612 hasLocation W20505846121 @default.
- W2050584612 hasOpenAccess W2050584612 @default.
- W2050584612 hasPrimaryLocation W20505846121 @default.
- W2050584612 hasRelatedWork W1983473138 @default.
- W2050584612 hasRelatedWork W1985249954 @default.
- W2050584612 hasRelatedWork W1989692008 @default.
- W2050584612 hasRelatedWork W1999545661 @default.
- W2050584612 hasRelatedWork W2005510807 @default.
- W2050584612 hasRelatedWork W2021290822 @default.
- W2050584612 hasRelatedWork W2049037714 @default.
- W2050584612 hasRelatedWork W2050584612 @default.
- W2050584612 hasRelatedWork W2063833217 @default.
- W2050584612 hasRelatedWork W2406210385 @default.
- W2050584612 hasVolume "317" @default.
- W2050584612 isParatext "false" @default.
- W2050584612 isRetracted "false" @default.
- W2050584612 magId "2050584612" @default.
- W2050584612 workType "article" @default.