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- W2050611812 abstract "The hydrogen and hydrogen peroxide produced in the radiolysis of CoIII-EDTA (CoIIIY−) in various pH’s have been measured. G∞(H2) in the deaerated system sharply dropped from the value of 3.2 at pH<1 to the value of 0.8 at pH>4 where G∞ denotes a limiting value which is reached with increasing solute concentration. G∞(H2O2) in the aerated system was found to be 2.5–2.0. G∞(–CoIIIY−) (=4.4) was not affected by the addition of N2O. G∞(N2) and G∞(H2) were found to be 2.6 and 0.8 respectively. From the results, it is concluded that H atoms and OH radicals reduce Co(III) to Co(II) through the dehydrogenation from the ligand, while eaq− reduce the complex without any degradation of the ligand." @default.
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- W2050611812 date "1968-06-01" @default.
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- W2050611812 title "Radiolysis of CoIII-EDTA in Aqueous Solution; The Effect of pH" @default.
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- W2050611812 doi "https://doi.org/10.1246/bcsj.41.1284" @default.
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