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• W2050640324 abstract "Two chromophores with diaza-18-crown-6 as receptor have been synthesized in high yields. The electronic structure, one-photon absorption (OPA) spectra, and two-photon absorption (TPA) properties have been studied in detail. When no metal ion is added as input, both show negligible TPA cross-section (σ2). However, in the presence of Zn(II)/Cd(II)/Mg(II)/Ca(II) ion, each exhibits large TPA cross-section value. Binding of metal ion in the receptor increases the symmetric charge transfer leading to large σ2 values. Theoretical calculations at the B3LYP functional with 6-31G∗ and LanL2DZ mixed basis set under DFT formalism support experimental results." @default.
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• W2050640324 date "2008-04-01" @default.
• W2050640324 modified "2023-10-18" @default.
• W2050640324 title "Diaza-18-crown-6 based chromophores for modulation of two-photon absorption cross-section by metal ions" @default.
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• W2050640324 doi "https://doi.org/10.1016/j.jorganchem.2008.01.019" @default.
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