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- W2050649065 abstract "Hydration and conformation of poly(methacrylic acid) in D2O (c = 0.036 g cm−3), neutralized by NaOD or LiOD, was studied by combination of neutron and X-ray small-angle scattering in the whole range of the degree of neutralization, α. Differences in the radii of gyration of polyion cross-section determined from the X-ray and neutron data indicate the existence of a monomolecular hydration shell, the density of which for α = 1 is about 10% higher than that of bulk water. Condensation of counterions on the polymer chain, increasing with α, has been proved. Persistence length is about 8 Å for α ⩽ 0.2, increases up to 12 Å for α ⋍ 0.2–0.5 and then remains constant." @default.
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- W2050649065 date "1986-08-01" @default.
- W2050649065 modified "2023-10-14" @default.
- W2050649065 title "Small-angle scattering by polyelectrolyte solutions. Hydration and conformation of poly(methacrylic acid)" @default.
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- W2050649065 doi "https://doi.org/10.1016/0032-3861(86)90013-3" @default.
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