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• W2050657526 abstract "The high-pressure/high-temperature behavior of boron has been investigated up to 30 GPa using x-ray diffraction techniques. We have investigated the isothermal compressibility of rhombohedral-105 $(Rensuremath{-}105)$ boron to 30.7 GPa, and determined the bulk modulus ${K}_{0T}$ to be $205(ifmmodepmelsetextpmfi{}16)mathrm{GPa}$ with ${K}_{0T}^{ensuremath{'}}=4.3(ifmmodepmelsetextpmfi{}1.6).$ We found that the a direction of $Rensuremath{-}105$ boron (hexagonal setting) is less compressible than c, which indicates that the B10-B-B10 chain is less rigid than the $B12$ cluster. High P-T studies were conducted using double-sided laser heating to temperatures of 3500 K. $Rensuremath{-}105$ boron transforms above 10 GPa at high temperature to a tetragonal phase that remains on P-T quenching. The transformation results in both a higher density and higher entropy phase and is consistent with the formation of the $Tensuremath{-}192$ phase of boron." @default.
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• W2050657526 date "2003-05-30" @default.
• W2050657526 modified "2023-10-13" @default.
• W2050657526 title "High-pressure high-temperature x-ray diffraction of β-boron to 30 GPa" @default.
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• W2050657526 doi "https://doi.org/10.1103/physrevb.67.174116" @default.
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