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• W2050668818 abstract "Poly(trimethylene carbonate) has been studied using the same approach as previously applied in the case of polylactide, polyglycollide and poly(ethylene oxalate). The degradation products consist almost entirely of trimethylene carbonate and small oligomers; the latter appear to be cyclic rather than linear. Acetylation of the hydroxyl chain ends stabilises the polymer considerably. An end-initiated ester interchange mechanism is suggested for the decomposition of poly(trimethylene carbonate), similar in some respects to the scheme proposed in the case of polyglycollide. Small amounts of carbon dioxide in the products, increasing with rise in degradation temperature, indicate some contribution from homolysis of the chain, but this reaction is much less important in this case than for the other polymers noted above." @default.
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• W2050668818 date "1989-01-01" @default.
• W2050668818 modified "2023-09-26" @default.
• W2050668818 title "Degradation studies of some polyesters and polycarbonates: Part 5—Poly(trimethylene carbonate)" @default.
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• W2050668818 doi "https://doi.org/10.1016/0141-3910(89)90133-x" @default.
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