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- W2050682013 abstract "Abstract The crystal and molecular structure of [Cu(nif)2(4-PM)2]·CH3OH (1) and [Cu(2-Clbz)2(4-PM)2(H2O)] (2), (where nif = niflumate anion, 2-Clbz = 2-chlorobenzoate anion and 4-PM is the 4-pyridylmethanol), have been determinated by X-ray crystallography. The Cu2+ cation in (1), is coordinated by two pairs of oxygen atoms from asymmetric bidentate niflumate anions and by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands in trans position forming an extremely elongated bipyramid. The Cu2+ cation in (2), is coordinated by a pair of oxygen atoms from monodentate 2-chlorobenzoate anions, further by a pair of pyridine nitrogen atoms from monodentate 4-pyridylmethanol ligands and finally by a water oxygen atom forming a tetragonal-pyramidal coordination polyhedron. The molecules of both complexes in crystal structures are linked by O-H…O hydrogen bonds, which created a three-dimensional hydrogen-bonding networks. The Π-Π stacking interactions are also observed in crystal structures of complex 2. The spectral properties (IR and electronic spectra) of both complexes were also investigated." @default.
- W2050682013 created "2016-06-24" @default.
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- W2050682013 date "2011-06-01" @default.
- W2050682013 modified "2023-10-14" @default.
- W2050682013 title "Self-assembled hydrogen-bonded coordination networks in two copper(II) carboxylates with 4-pyridylmethanol" @default.
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- W2050682013 doi "https://doi.org/10.2478/s11532-011-0023-9" @default.
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