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• W2050739968 abstract "Anode material Li4Ti5O12 for lithium-ion batteries have been synthesized by a novel sol–gel method with triethanolamine(TEA) as a chelating agent and LiAc · 2H2O and Tetrabutyl titanate [Ti (OC4H9) 4] as starting materials. Various initial conditions were studied in order to find the optimal conditions for the synthesis of Li4Ti5O12. The as-prepared samples have been characterized by means of XRD, IR and SEM. Its electrochemical behavior was evaluated in a liquid electrolyte in lithium-ion batteries. These analyses indicated that the prepared Li–Ti–O powders belonged to a spinel structure and had a uniform morphology with average particle size from 223 to 105 nm with the increase in TEA content. At 1.55 V (vs. Li), the Li4Ti5O12 electrode with the ratio of TEA to Ti ions 0.8 exhibited an initial discharge capacity of 168 mA h/g and a subsequent charge capacity of 151 mA h/g. The results of cyclic voltammetry for Li4Ti5O12 showed that at the potential range from 1.5 to 1.7 V (vs. Li), there was a pair of reversible redox peaks correspond to the process of Li+ intercalation and de-intercalation in the spinel Li–Ti–O oxides." @default.
• W2050739968 created "2016-06-24" @default.
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• W2050739968 date "2005-04-29" @default.
• W2050739968 modified "2023-10-14" @default.
• W2050739968 title "Synthesis by TEA sol–gel method and electrochemical properties of LiTiO anode material for lithium-ion battery" @default.
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• W2050739968 doi "https://doi.org/10.1016/j.ssi.2005.02.010" @default.
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