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- W2050740827 abstract "Ternary copolymerization of tri-n-butyltin acrylate (TBTA) or methylacrylate (TBTMA) with itaconic acid (IA) or dimethyl itaconate (DMI) and acrylonitrile (AN) were carried out in solution at 70°C in the presence of a free radical initiator. Experimental terpolymerization data agreed well with calculations based on the Alfrey-Goldfinger equation. Ternary azeotropic compositions for TBTA-IA-AN, TBTMA-IA-IA, and TBTMA-DMI-AN systems were 39.0 : 26.1 : 34.9, 51.7 : 10.5 :37.8, and 00.3 : 66.3 : 33.4 mol %, respectively. Also, “pseudo-azeotropic” regions were indentified where the deviation between feed and polymer compositions is very small." @default.
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- W2050740827 date "1992-04-05" @default.
- W2050740827 modified "2023-10-16" @default.
- W2050740827 title "Organotin polymers. XV. Azeotropy in terpolymerization reactions of tributyltin acrylate or methacrylate with itaconic acid or dimethylitaconate and acrylonitrile" @default.
- W2050740827 doi "https://doi.org/10.1002/app.1992.070441021" @default.
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