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• W2050745556 startingPage "2369" @default.
• W2050745556 abstract "Single-crystal ESR studies have been carried out on symmetrical triphenylverdazyl (TPV) doped in a diamagnetic 1,3,5-triphenylbenzene (TPB) crystal at room temperature. There have appeared seven pairs of fine-structure absorptions in addition to the hyperfine splittings. Three out of the seven pairs have been assigned as zero-field splittings due to radical pairs, while the other three pairs have been identified as from radical triads. The six fine structure tensors have been determined through the angular variation of the resonance-field separations. The structures of the pairs and triads of TPV were discussed on the basis of the fine structure tensors, the crystal structures of TPB and TPV, and the spin distribution in the radical molecule, assuming that the unit cell of the mixed crystal with the radical concentration of less than 11.1% is identical with that of the host crystal, TPB. Within the limits of the X-ray examination, this assumption was found to be reliable. It was found that the molecular planes in each species are almost parallel to the bc-plane and that all the C-phenyl rings lie in the c-direction." @default.
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• W2050745556 date "1974-10-01" @default.
• W2050745556 modified "2023-09-27" @default.
• W2050745556 title "The Magnetic Properties of Verdazyl Free Radicals. VI. ESR Studies of Pairs and Triadst of the Symmetrical Triphenylverdazyl Radical in the 1,3,5-Triphenylbenzene Matrix" @default.
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• W2050745556 doi "https://doi.org/10.1246/bcsj.47.2369" @default.
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