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• W2050786799 endingPage "116" @default.
• W2050786799 startingPage "109" @default.
• W2050786799 abstract "We have studied the reactions D+2 + H2 → D2H+ + H and H+2 + D2 → (H2D+, D2H+) + (D, H) using the crossed-beam apparatus EVA. Sample contour velocity distributions of product ions have been obtained at relative kinetic energies between 0.4 and 5 eV. In addition potential energy surfaces were constructed for H+4 by the diatomics-in-molecules method and representative geometries were investigated. The experimental results are consistent with the predominant early downhill nature of the ground-state surface, in that a direct mechanism is observed at all energies studied. As the reactants approach one another, avoided surface crossings leading to charge transfer are accessible. Because of the occurrence of repeated electron jumps, the initial identity of the molecular ion is largely inconsequential and it is meaningless to label the mechanism as atom or ion transfer" @default.
• W2050786799 created "2016-06-24" @default.
• W2050786799 creator A5010485077 @default.
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• W2050786799 date "1976-08-01" @default.
• W2050786799 modified "2023-09-25" @default.
• W2050786799 title "Crossed-beam study of the reactions of H+2 with D2 and D+2 with H2" @default.
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• W2050786799 doi "https://doi.org/10.1016/0301-0104(76)89028-3" @default.
• W2050786799 hasPublicationYear "1976" @default.
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