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• W2050813156 abstract "Nitrided Sm2Fe17-based materials possess excellent intrinsic magnetic properties, and in this study we have investigated two compositions: Sm13.8Fe82.2Ta4.0 (SmFeTa) and Sm13.7Fe86.3 (SmFe). The stoichiometry of all the phases was determined and the SmFeTa material was found to include Ta3Fe7 in addition to the Sm2Fe17, SmFe2 and SmFe3 phases observed in the SmFe alloy, however, it did not exhibit the α-iron dendrites that are characteristic of the binary material. Hydrogen absorption-desorption studies carried out on both materials using thermopiezic and gas-flow analyses demonstrated the different hydrogenation-disproportionation-desorption-recombination (HDDR) behaviour of the SmFeTa alloy. Scanning and transmission electron microscopy studies revealed that in the as-cast structure some 2.0 at.% of Ta is initially dissolved in the Sm2(FeTa)17 phase, however, a single HDDR cycle causes the formation of Ta-based precipitates leaving the 2:17 with much less dissolved Ta." @default.
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• W2050813156 date "2002-10-01" @default.
• W2050813156 modified "2023-10-18" @default.
• W2050813156 title "Hydrogen absorption and desorption in Ta-doped SmFe-based alloys" @default.
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• W2050813156 doi "https://doi.org/10.1016/s0925-8388(02)00329-8" @default.
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