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- W2050829574 abstract "Treatment of trans-[ReCl(CNR)(dppe)2] (R = Me or But, dppe = Ph2PCH2CH2 PPh2) with CoCl2(THF)1.5, [ReOCl3(PPh3)2] or [WCl4L2] (L = PPh3 or PEtPh2) affords the dinuclear adducts [ReCl(CN(M)R)(dppe)2] (M = CoCl2(THF), ReOCl3(PPh3) or WCl4L, respectively) (formed via electrophilic β-addition of the electron-acceptor molecules to the isocyanide ligands), which undergo dissociation oxidation (for M = CoCl2(THF) or ReOCl3(PPh3)). These reactions are considered in the light of results of extended Hückel calculations." @default.
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- W2050829574 date "1989-07-01" @default.
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- W2050829574 title "Synthesis of transition-metal Lewis acid adducts of trans-[ReCl(CNR)(Ph2PCH2CH2PPh2)2] (R = alkyl). A chemical and a quantum-chemical study of electrophilic β-addition to ligating isocyanide" @default.
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- W2050829574 doi "https://doi.org/10.1016/0022-328x(89)85221-0" @default.
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