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- W2050870188 abstract "Abstract Using a laser flash photolysis/laser probe technique, applied to two different gaseous precursor molecules, we report absorption signals in the wavenumber region 17109–17120 cm −1 , attributable to previously unobserved rotational transitions in the vibronic spectrum of GeH 2 . By time-resolved monitoring of GeH 2 , rate constants have been obtained for its reactions with O 2 , C 2 H 2 , i-C 4 H 8 , 1,3-C 4 H 6 , C 3 H 8 and Me 3 SiH. The measurements show that GeH 2 is unreactive towards CH bonds but inserts readily in SiH bonds, as well as reacting rapidly (close to the collision rate), with π-bonds. These results represent the first direct kinetic measurements on GeH 2 . Comparisons show that it is slightly less reactive than SiH 2 ." @default.
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- W2050870188 date "1996-09-01" @default.
- W2050870188 modified "2023-09-25" @default.
- W2050870188 title "Room temperature observation of GeH2 and the first time-resolved study of some of its reactions" @default.
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- W2050870188 doi "https://doi.org/10.1016/0009-2614(96)00855-x" @default.
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