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• W2050872350 abstract "The 1:2 Lewis adducts of zirconium tetrachloride (ZrCl4) and cyclopentadienylzirconium trichloride (CpZrCl3) with tetrahydrofuran (THF) have been studied in solutions by means of X-ray absorption spectroscopy. The organometallic complex CpZrCl3(THF)2 has in THF solution a structure similar to the known crystallographic solid state structure. In solution the average zirconium-carbon distance is 0.06 A longer, and the average Zr-oxygen distance as well as the average Zr-chlorine distance are 0.05 A shorter than in the solid state. In the inorganic complex ZrCl4(THF)2 the zirconium-oxygen distance is short (2.22 A), and the trans influence difference between chloride and tetrahydrofuran ligands gives two experimentally separable zirconium-chlorine distances (2.39 A and 2.49 A)." @default.
• W2050872350 created "2016-06-24" @default.
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• W2050872350 date "1994-07-01" @default.
• W2050872350 modified "2023-09-27" @default.
• W2050872350 title "An EXAFS investigation of the Lewis acids zirconium tetrachloride and cyclopentadienylzirconium trichloride in tetrahydrofuran solutions" @default.
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• W2050872350 doi "https://doi.org/10.1002/bbpc.19940980709" @default.
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