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- W2050885087 abstract "Passive films on AISI 304 and 316 stainless steels in a near-neutral 0.5 M NaCl solution were studied using potentiodynamic, impedance and photoelectrochemical techniques. The results obtained indicate that passive films on both steels show the characteristics of an amorphous or disordered n-type semiconductor. The passive film on molybdenum-containing stainless steel has a lower donor concentration than that on 304 stainless steel. During the ageing process the donor concentration in passive films on both steels decreases. The shift of the Mott-Schottky line with pH change and consequently the pH dependence of the flat-band potential is assumed to be caused by an acid-base equilibrium established at the passive film/solution interface. Potential dependence of the optical gap value is observed and is interpreted on the basis of the passive film composition." @default.
- W2050885087 created "2016-06-24" @default.
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- W2050885087 date "1993-11-01" @default.
- W2050885087 modified "2023-09-26" @default.
- W2050885087 title "Semiconducting properties of passive films on AISI 304 and 316 stainless steels" @default.
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- W2050885087 doi "https://doi.org/10.1016/0022-0728(93)80435-k" @default.
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