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- W2050899863 abstract "A method is described of studying ion/molecule kinetics in a Fourier-transform ion cyclotron resonance spectrometer of ions produced at precursor pressures of 6 × 10−9 mBar with a neutral gas introduced through a pressure pulse of variable time. The analysis of the kinetic curves of the proton-transfer reactions of C3H cations to CH3OH yields either single or double exponential decays that can readily be used to obtain the percentages of allyl and 2-propenyl cations produced by different precursors. Allyl bromide is shown to produce 100% allyl cations while 2-bromopropene at 13 eV yields roughly 74% of 2-propenyl and 26% of allyl cations." @default.
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- W2050899863 date "1991-09-01" @default.
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- W2050899863 title "A kinetic method of distinguishing isomeric C3H5+ cations" @default.
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- W2050899863 doi "https://doi.org/10.1002/rcm.1290050903" @default.
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