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- W2050915372 abstract "It is well known that the open-cell voltage (U) of a galvanic cell involving a binary compound, or a multinary compound with a single kind of mobile ionic species, is a state property under a gradient of chemical potential of the mobile component. It is not so transparent, however, whether U is still a state property when involving a ternary or multinary compound with two or more kinds of mobile ions under multiple chemical potential gradients of those mobile components. We clarify this issue with a multinary oxide that conducts oxide ions, protons and electron holes and is exposed to the chemical potential gradients of both water and oxygen. We show that U is path- and history-dependent, and manifests itself along the diffusion paths of the two mobile components H and O under given boundary conditions." @default.
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- W2050915372 date "2010-01-01" @default.
- W2050915372 modified "2023-09-27" @default.
- W2050915372 title "On the path-dependence of the open-cell voltage of a galvanic cell involving a ternary or multinary compound with multiple mobile ionic species under multiple chemical potential gradients" @default.
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- W2050915372 doi "https://doi.org/10.1039/c0cp00977f" @default.
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