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- W2050928811 abstract "Abstract The electrochemical behaviour of molybdenum(VI) in sulphuric acid solutions was investigated by cyclic voltammetry. In the reduction of Mo(VI) to Mo(III) a dimerization reaction of Mo(V) is involved; the rate constant for the reaction was estimated to be 2.79×102 M−1 s−1 and the activation energy was ca. 35 kJ mol−1 in 0.1 M H2O4. Oxidation of the monomer and dimer Mo(V) species take place at −0.31 and +0.18 V (vs. SCE), respectively." @default.
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- W2050928811 date "1987-02-01" @default.
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- W2050928811 title "Dimerization of electrogenerated Mo(V) in sulphuric acid solutions" @default.
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- W2050928811 doi "https://doi.org/10.1016/0022-0728(87)80226-7" @default.
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