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- W2050934843 abstract "Small volume electrochemical cells are required for the analysis of biological fluids or clinical samples and for the construction of small size sensors [l]. IDA electrodes are particularly useful for the detection of redox species in a small volume sample because their diffusion layers are time independent and are formed only between two IDA finger electrodes [2, 31. IDAs are also useful for suppressing consumption of the redox species during measurement because the redox cycling between the two IDA electrodes causes the analyte to revert to its initial state at the cathode. This redox cycling also enhances the signal and enables a low detection limit to be realized [4]. IDA electrode cells will be applied to detect selectively reversible species in the presence of an irreversible interferent by removing it with continuous electrolysis at one electrode and collecting only the reversible species at the other. In this paper, we report the highly sensitive detection of redox species using a small IDA electrode cell and apply it to the selective detection of dopamine in the presence of L-ascorbic acid." @default.
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- W2050934843 date "1993-06-01" @default.
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- W2050934843 title "Highly sensitive small volume voltammetry of reversible redox species with an IDA electrochemical cell and its application to selective detection of catecholamine" @default.
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- W2050934843 doi "https://doi.org/10.1016/0925-4005(93)85090-w" @default.
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