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• W2050956871 abstract "The aerobic photocatalysed oxidation of alkanes in the presence of decatungstates Q4W10O32(Q = Na, Me4N, Pr4N, Bu4N, Hex4N) leads to hydroperoxides as primary products. Nitrile solvents and organic counter-ions of the catalyst compete in this photooxidation with alkane substrate. The influence of this competition on quantum yield, rate and selectivity for the oxidation of adamantane is quantitatively evaluated. A catalytic cycle, describing the formation of primary and secondary oxidation products, is proposed." @default.
• W2050956871 created "2016-06-24" @default.
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• W2050956871 date "1996-01-01" @default.
• W2050956871 modified "2023-10-17" @default.
• W2050956871 title "Aerobic photocatalysed oxidation of alkanes in the presence of decatungstates: products and effects of solvent and counter-ion of the catalyst" @default.
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• W2050956871 doi "https://doi.org/10.1039/p29960001205" @default.
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