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- W2050976912 abstract "We have investigated the crystal nucleation behavior of potassium hexacyanoferrate(III) (KFC) in an isolated aqueous microdroplet surrounded by a decanol medium which is isothermally driven to supersaturation by water transport from the droplet, to examine the influence upon KFC nucleation by self-assembled surfactant monolayers at the liquid−liquid interface. The nucleation behavior was studied by measurement of the level of supersaturation required for the onset of crystallization (Sonset) based on microscopic observation. For KFC crystallization in the absence of surfactant, it was found that Sonset was 1.74 ± 0.13. This value was independent of droplet initial size (80−160 μm) and initial KFC concentration (10−40%). In the presence of a minimum threshold concentration of octadecylamine (ODA) in decanol, the Sonset value was diminished significantly (1.41 ± 0.06), indicative of templated nucleation acceleration. Additionally, the crystal habit for KFC grown in the presence of ODA monolayer was markedly more regular than in the absence of monolayer. Neither octadecylammonium chloride (ODA·HCl) nor stearic acid showed any templating effect. Mixed ODA−ODA·HCl monolayers exhibited intermediate effects. The results are explained in terms of ODA monolayer as a template for nucleation due to a combination of both electrostatic interactions and structural matching." @default.
- W2050976912 created "2016-06-24" @default.
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- W2050976912 date "2009-05-04" @default.
- W2050976912 modified "2023-10-04" @default.
- W2050976912 title "Controlled Nucleation of K<sub>3</sub>Fe(CN)<sub>6</sub> in Isolated Microdroplets at Liquid−Liquid Interface" @default.
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- W2050976912 doi "https://doi.org/10.1021/cg801199e" @default.
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