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- W2051016543 abstract "Abstract The kinetics of electroreduction of hexakis(dimethylformamide)chromium(III) in dimethylformamide have been studied at a mercury electrode in the presence of tetraethylammonium and lithium perchlorates. A detailed study of double layer effects shows that the trivalent cation is predominantly ion paired in the bulk of the solution and that both the unpaired and ion paired species are present at the reaction site in the double layer. The real heat of activation has been determined from a study of the temperature dependence of the rate constant. Double layer corrected kinetic parameters have been estimated, and used together with an estimate of the real entropy of activation to calculate the pre-exponential factor for the reaction. The kinetic parameters obtained here have been compared with those obtained in previous studies of the reduction of hexaquochromium(III) in water and discussed within the context of the theory of heterogeneous electron transfer." @default.
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- W2051016543 date "1989-10-01" @default.
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- W2051016543 title "The kinetics of electroreduction of Cr(III) at mercury in dimethylformamide solutions" @default.
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- W2051016543 doi "https://doi.org/10.1016/0022-0728(89)85031-4" @default.
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