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- W2051041730 abstract "For the purpose of improving the accuracy and precision of tritium measurements in natural waters, this paper proposes a new method for the estimation of tritium concentration after electrolytic enrichment. The proposed method was based on the fact that there is a reliable correlation between the water electrolytic enrichment of deuterium and that of tritium. The constancy of the ratio, k, during the electrolysis, k = α(β − 1)/β(α − 1), was experimentally verified, where α and β are the separation factors of deuterium and tritium, respectively. The value of k depends only on the electrode materials and the type of cells. The value of k is far more constant than the values of βα and of log β/log α. When the value of k was experimentally measured beforehand, the initial concentration of sample water, (T/H)0, could be estimated by the formula (T/H)0 = (T/H)f[(D/H)f(D/H)0]−k, where (T/H)f and (D/H)f are the tritium and deuterium contents after the electrolysis, and (D/H)0 is the deuterium content before the electrolysis." @default.
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- W2051041730 date "1991-01-01" @default.
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- W2051041730 title "Natural tritium measurements: Determination of the electrolytic enrichment factor of tritium" @default.
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- W2051041730 doi "https://doi.org/10.1016/0883-2889(91)90178-4" @default.
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