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- W2051052884 abstract "Cationic palladacycles of the general formula [{o-C6H4(CH2)N(R)2Pd(P⌒P)}][X] (P⌒P = Ph2P(CH2)3PPh2, (PhCH2)2C(CH2PPh2)2; X = Cl, PF6, B(C6H5)4; R = H, CH3, CH2C6H5) and [{o-(CH2)C6H4P(o-Tol)2Pd(P⌒P)}][X] (P⌒P = Ph2P(CH2)3PPh2; X = Cl, PF6) have been prepared and structurally characterized in the former case (X-ray structure analysis for X = PF6, R = CH3). They are resistant to air and moisture, both in solution and the solid state, and represent one of the most active single-component catalyst systems for the perfectly alternating C2H4/CO copolymerization in aprotic solvents. Stoichiometric model reactions provide insight into the mechanism, suggesting that insertion of carbon monoxide into the carbon−palladium(II) bond initiates the catalytic cycle." @default.
- W2051052884 created "2016-06-24" @default.
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- W2051052884 date "2000-07-11" @default.
- W2051052884 modified "2023-10-14" @default.
- W2051052884 title "Highly Efficient Monocationic Palladacycles of Chelating Diphosphines in C<sub>2</sub>H<sub>4</sub>/CO Copolymerization" @default.
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- W2051052884 doi "https://doi.org/10.1021/om0000212" @default.
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