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• W2051060831 startingPage "1161" @default.
• W2051060831 abstract "The effect of temperature over the range −196 to 150°C on the crosslinking of polyethylenes irradiated by electron beam has been investigated on the basis of gel content determination and Fourier transform infra-red (FTIR) spectroscopy. The crosslinking efficiency increases significantly with increasing irradiation does and at elevated irradiation temperature. The crosslinking rates of high density polyethylene (HDPE) and low density polyethylene (LDPE) samples above the melting point (TM) are much higher than those below Tm. The FTIR data give positive evidence: (i) that trans-vinylene double bonds in cross linked HDPE and LDPE samples increase with increasing irradiation dose temperature (ii) that vinyl double bonds in HDPE decrease rapidly with increasing irradiation dose and temperature, and (iii) vinylidene groups in LDPE decrease slowly with increasing temperature at the lower dose and are almost independent of the irradiation temperature at above room temperature and the higher dose of more than 100 kGy. Gas bubbles are observed in LDPE samples irradiated at 100 and 150°C with high dose (200 to 250 kGy). The size of the bubbles increases gradually at high temperatures." @default.
• W2051060831 created "2016-06-24" @default.
• W2051060831 creator A5069295515 @default.
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• W2051060831 date "1995-07-01" @default.
• W2051060831 modified "2023-10-17" @default.
• W2051060831 title "Radiation crosslinking of polyethylene with electron beam at different temperatures" @default.
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• W2051060831 doi "https://doi.org/10.1002/pen.760351406" @default.
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