Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051082258> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W2051082258 abstract "This paper deals with the study of redox reactions of Cr(II) ions with hydroxylamine, hydrazoic acid, maleic acid, di- and trichloroacetic acids in so-called typically aqueous mixtures of water with methyl alcohol, isopropyl alcohol, or tert-butyl alcohol. The kinetics of the redox reaction with dichloroacetic acid was studied also in the medium of aqueous acetone and in a typically nonaqueous medium water-acetonitrile. The dependences of activation Gibbs energies on the mole fraction of the nonaqueous component have no minima and maxima characteristic for the thermodynamic behaviour of the mentioned binary systems. However, the change of the activation Gibbs energy with the mole fraction of tert-butyl alcohol is not monotonous with all the studied reactions of Cr(II) ions. At a constant mole fraction of the nonaqueous component, the usual trend of the influence on the rate constants decreases in the sequence tert-butyl alcohol > isopropyl alcohol > methyl alcohol. Tert-butyl alcohol hinders most strongly the redox reaction with trichloroacetic acid, whereas it accelerates the reaction of Cr(II) ions with maleic acid and hydroxylamine." @default.
- W2051082258 created "2016-06-24" @default.
- W2051082258 creator A5005752095 @default.
- W2051082258 creator A5071789940 @default.
- W2051082258 date "1981-01-01" @default.
- W2051082258 modified "2023-10-12" @default.
- W2051082258 title "Influence of solvent on kinetics of reactions of Cr(II) ions" @default.
- W2051082258 doi "https://doi.org/10.1135/cccc19811554" @default.
- W2051082258 hasPublicationYear "1981" @default.
- W2051082258 type Work @default.
- W2051082258 sameAs 2051082258 @default.
- W2051082258 citedByCount "4" @default.
- W2051082258 crossrefType "journal-article" @default.
- W2051082258 hasAuthorship W2051082258A5005752095 @default.
- W2051082258 hasAuthorship W2051082258A5071789940 @default.
- W2051082258 hasConcept C121332964 @default.
- W2051082258 hasConcept C132439834 @default.
- W2051082258 hasConcept C145148216 @default.
- W2051082258 hasConcept C148898269 @default.
- W2051082258 hasConcept C155647269 @default.
- W2051082258 hasConcept C178790620 @default.
- W2051082258 hasConcept C179104552 @default.
- W2051082258 hasConcept C185592680 @default.
- W2051082258 hasConcept C2780471494 @default.
- W2051082258 hasConcept C62520636 @default.
- W2051082258 hasConceptScore W2051082258C121332964 @default.
- W2051082258 hasConceptScore W2051082258C132439834 @default.
- W2051082258 hasConceptScore W2051082258C145148216 @default.
- W2051082258 hasConceptScore W2051082258C148898269 @default.
- W2051082258 hasConceptScore W2051082258C155647269 @default.
- W2051082258 hasConceptScore W2051082258C178790620 @default.
- W2051082258 hasConceptScore W2051082258C179104552 @default.
- W2051082258 hasConceptScore W2051082258C185592680 @default.
- W2051082258 hasConceptScore W2051082258C2780471494 @default.
- W2051082258 hasConceptScore W2051082258C62520636 @default.
- W2051082258 hasLocation W20510822581 @default.
- W2051082258 hasOpenAccess W2051082258 @default.
- W2051082258 hasPrimaryLocation W20510822581 @default.
- W2051082258 hasRelatedWork W1965507974 @default.
- W2051082258 hasRelatedWork W1966539936 @default.
- W2051082258 hasRelatedWork W1981607825 @default.
- W2051082258 hasRelatedWork W1991926860 @default.
- W2051082258 hasRelatedWork W2020064164 @default.
- W2051082258 hasRelatedWork W2033218590 @default.
- W2051082258 hasRelatedWork W2033684962 @default.
- W2051082258 hasRelatedWork W2034513591 @default.
- W2051082258 hasRelatedWork W2041857868 @default.
- W2051082258 hasRelatedWork W2044222210 @default.
- W2051082258 hasRelatedWork W2044471252 @default.
- W2051082258 hasRelatedWork W2326661208 @default.
- W2051082258 hasRelatedWork W2328721139 @default.
- W2051082258 hasRelatedWork W2796736128 @default.
- W2051082258 hasRelatedWork W288092137 @default.
- W2051082258 hasRelatedWork W2950486954 @default.
- W2051082258 hasRelatedWork W3137383543 @default.
- W2051082258 hasRelatedWork W342025684 @default.
- W2051082258 hasRelatedWork W78042680 @default.
- W2051082258 hasRelatedWork W2522737275 @default.
- W2051082258 isParatext "false" @default.
- W2051082258 isRetracted "false" @default.
- W2051082258 magId "2051082258" @default.
- W2051082258 workType "article" @default.