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- W2051101540 abstract "Abstract Hexabutyl guanidinium acetate (HBG · OAc) was synthesized and successfully used as a catalyst for the ring‐opening polymerization (ROP) of lactides. The experimental results indicated that the guanidinium salt HBG · OAc showed satisfactory catalytic behavior. Polymerization in bulk (120 °C, 18 h) produced polylactides with moderate molecular weights (number‐average molecular weight = 2.0 × 10 4 ) and very narrow molecular weight distributions (polydispersity index = 1.07–1.12). A kinetic study of polymerization in bulk with HBG · OAc as an initiator revealed that the polymerization possessed typical characteristics of living polymerization. A ROP mechanism by HBG · OAc was proposed on the basis of the additive effect of the polymerization and the 1 H NMR characterization of the microstructure of the product polymers. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3775–3781, 2004" @default.
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- W2051101540 date "2004-06-22" @default.
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- W2051101540 title "Living ring-opening polymerization of lactides catalyzed by guanidinium acetate" @default.
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- W2051101540 doi "https://doi.org/10.1002/pola.20275" @default.
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