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- W2051102905 abstract "The heterobinuclear complexes [CdMoO2(L)3(H2O)] (L = diethyldithiocarbamate, 4-morpholinyldithiocarbamate, 1-piperidenylthiocarbamate or 8-quinolinol) were prepared by the interaction of cadmium(II) molybdate with the respective ligands in dimethylformamide. The magnetic moment, EPR and PES spectral studies suggested the presence of molybdenum in the pentavalent state. The IR spectral bands suggested the presence of MoO (920 cm−1) and CdOMo (780 cm−1) and bidentate dithiocarbamate ligands in the molecule. The IR, PES and thermal decomposition studies confirmed the presence of a coordinated water molecule. The 1H and 13C NMR chemical shifts indicated van der Wall's interactions between a set of protons coming closer due to the proximity of the dithiocarbamate ligands coordinated to the heterometal atoms. The proposed structure consists of a tetrahedral cadmium(II) and octahedral molybdenum(V) bridged by an oxo group." @default.
- W2051102905 created "2016-06-24" @default.
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- W2051102905 date "1992-01-01" @default.
- W2051102905 modified "2023-09-25" @default.
- W2051102905 title "Cadmium-molybdenum complexes of dithiocarbamates and 8-quinolinol" @default.
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- W2051102905 doi "https://doi.org/10.1016/s0277-5387(00)83280-5" @default.
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