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- W20511201 abstract "ABSTRACT Direct measurements have been made of adsorption at the nitrogen-solution interface of sodium dodecyl sulphate (SDS), mono-octyltetraethylene glycol and their mixtures using a radiotracer technique. Changes in the surface tension of aqueous solutions of the mixtures have been compared with those calculated from surface excess concentrations, giving good agreement via the Gibbs’ adsorption equation. For the mixed surfactant system, micellar compositions were calculated from critical micelle concentration data (CMC) and surface compositions from the surface tension data of the single surfactants, on the basis of regular solution mixing, and compared with experimental surface compositions. Both the calculated micellar and experimental surface compositions showed a change from anionic rich to nonionic rich as the fraction of SDS was increased, with the cross-over point moving towards higher bulk SDS content as electrolyte (NaCl) was added." @default.
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- W20511201 date "1983-01-01" @default.
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- W20511201 title "DIRECT MEASUREMENTS OF MIXED SURFACTANT CONCENTRATIONS AT THE GAS-LIQUID INTERFACE AND THEIR RELATION TO MICELLAR COMPOSITIONS" @default.
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- W20511201 doi "https://doi.org/10.1016/b978-0-12-530980-6.50014-0" @default.
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