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- W2051140875 abstract "A series of functionalised 2,2′:6′,2″-terpyridine ligands, each with a closo-1,2-C2B10H10R (R=H or SitBuMe2) substituent in the 4′ position, either directly or indirectly attached to the heterocyclic ring, has been prepared; two members of the series, 4′-(3-ortho-carboranylpropoxy)-2,2′:6′,2″-terpyridine (4) and 4′-(ortho-carboranyl)-2,2′:6′,2″-terpyridine (7) have been characterised by X-ray crystallography. The reaction of ligand (7) with alcohols results in the boron decapping of the closo-cage and yields a Zwitter-ionic nido-cluster-functionalised ligand. Analogous changes to the carbaborane cage have been observed in complexes in which the terpyridine domain is coordinated to ruthenium(II). However, decapping does not occur if a SitBuMe2-protected carbaborane cage is incorporated into the terpyridine ligands." @default.
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- W2051140875 date "1998-01-01" @default.
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- W2051140875 title "Carbaborane-functionalised 2,2′:6′,2″-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4′-(ortho-carboranyl)-2,2′:6′,2″-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2″-terpyridine1This paper is dedicated to Professor Ken Wade on the occasion of his 65th birthday.1" @default.
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- W2051140875 doi "https://doi.org/10.1016/s0022-328x(97)00238-6" @default.
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