Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051155563> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2051155563 endingPage "78" @default.
- W2051155563 startingPage "69" @default.
- W2051155563 abstract "Rheniumpentachlorid reagiert in POCl3-Lösung mit trimerem Thiazylchlorid (NSCl)3, unter Bildung der Chlorthionitrenkomplexe [(Cl3PO)ReCl4(NSCl)] (I) bzw.[(Cl3PO)ReCl3 (NSCl)2] (II). I reagiert mit AsPh4Cl in Dichlormethanlösung unter Abspaltung von Schwefeldichlorid und Phosphorylchlorid zu AsPh4[ReNCl4], während II mit AsPh4Cl den Komplex AsPh4-[ReCl4(NSCl)2] · CH2Cl2 bildet. Die IR-Spektren der Verbindungen werden diskutiert und zugeordnet. Die Kristallstruktur von AsPh4[ReCl4(NSCl)2] · CH2Cl2 wurde mit Hilfe von Röntgenbeugungsdaten ermittelt und verfeinert (R-Wert 3,1% für 2785 Reflexe). Es kristallisiert triklin in der Raumgruppe PĪ mit zwei Formeleinheiten pro Elementarzelle und den Gitterkonstanten a = 1119, b = 1144, c = 1473 pm, α = 77,6, β 70,8 und γ 71,2°. Die beiden NSCl-Liganden sind cis-ständig an das Rhenium gebunden, mit fast gestreckten ReNS-Gruppierungen, deren interatomare Abstände als Doppelbindungen aufzufassen sind. Die ReCl-Abstände sind etwas länger als sonst und lassen keinen trans-Effekt erkennen; dies kann mit H-Brückenbindungen Cl…︁HC zusammenhängen. Chlorothionitrene Complexes of Rhenium. Crystal Structure of AsPh4[ReCl4(NSCl)2] · CH2Cl2 Rhenium pentachloride reacts in POCl3 solution with (NSCl)3 forming the chlorothionitrene complexes [(Cl3PO)ReCl4(NSCl)] (I) and [(Cl3PO)ReCl3(NSCl)2] (II). I reacts with AsPh4Cl in CH2Cl2 solution under abstraction of SCl2 and POCl3, yielding AsPh4[ReNCl4], while II forms the complex AsPh4[ReCl4(NSCl)2] · CH2Cl2. The i.r. spectra of the compounds are discussed and assigned. The crystal structure of AsPh4[ReCl4(NSCl)2] · CH2Cl2 was determined and refined with X-ray diffraction data (R = 0.031 for 2785 reflexions). It crystallizes in the space group PĪ with two formula units per unit cell; the lattice constants are a = 1119, b = 1144, c = 1473 pm, α = 77.6, β = 70.8 and γ = 71.2°. The two NSCl ligands have cis arrangement with nearly linear ReNS groups, with interatomic distances corresponding to double bonds. The ReCl bonds are somewhat longer than usual and show no trans-effect; this is possibly due to Cl…︁HC bridges." @default.
- W2051155563 created "2016-06-24" @default.
- W2051155563 creator A5038113350 @default.
- W2051155563 creator A5042683024 @default.
- W2051155563 creator A5069251556 @default.
- W2051155563 date "1983-06-01" @default.
- W2051155563 modified "2023-10-18" @default.
- W2051155563 title "Chlorthionitrenkomplexe des Rheniums Die Kristallstruktur von AsPh4[ReCl4(NSCl)2] � CH2Cl2" @default.
- W2051155563 cites W1976602046 @default.
- W2051155563 cites W1987015434 @default.
- W2051155563 cites W2019814398 @default.
- W2051155563 cites W2024059248 @default.
- W2051155563 cites W2031009106 @default.
- W2051155563 cites W2037421628 @default.
- W2051155563 cites W2051874861 @default.
- W2051155563 cites W2066636804 @default.
- W2051155563 cites W2068625088 @default.
- W2051155563 cites W2073614125 @default.
- W2051155563 cites W2076072465 @default.
- W2051155563 cites W2085449097 @default.
- W2051155563 cites W2091754902 @default.
- W2051155563 cites W2095152565 @default.
- W2051155563 cites W2124830092 @default.
- W2051155563 doi "https://doi.org/10.1002/zaac.19835010608" @default.
- W2051155563 hasPublicationYear "1983" @default.
- W2051155563 type Work @default.
- W2051155563 sameAs 2051155563 @default.
- W2051155563 citedByCount "26" @default.
- W2051155563 crossrefType "journal-article" @default.
- W2051155563 hasAuthorship W2051155563A5038113350 @default.
- W2051155563 hasAuthorship W2051155563A5042683024 @default.
- W2051155563 hasAuthorship W2051155563A5069251556 @default.
- W2051155563 hasConcept C115624301 @default.
- W2051155563 hasConcept C155647269 @default.
- W2051155563 hasConcept C178790620 @default.
- W2051155563 hasConcept C185592680 @default.
- W2051155563 hasConcept C505216180 @default.
- W2051155563 hasConcept C71240020 @default.
- W2051155563 hasConcept C8010536 @default.
- W2051155563 hasConceptScore W2051155563C115624301 @default.
- W2051155563 hasConceptScore W2051155563C155647269 @default.
- W2051155563 hasConceptScore W2051155563C178790620 @default.
- W2051155563 hasConceptScore W2051155563C185592680 @default.
- W2051155563 hasConceptScore W2051155563C505216180 @default.
- W2051155563 hasConceptScore W2051155563C71240020 @default.
- W2051155563 hasConceptScore W2051155563C8010536 @default.
- W2051155563 hasIssue "6" @default.
- W2051155563 hasLocation W20511555631 @default.
- W2051155563 hasOpenAccess W2051155563 @default.
- W2051155563 hasPrimaryLocation W20511555631 @default.
- W2051155563 hasRelatedWork W2005871967 @default.
- W2051155563 hasRelatedWork W2007867934 @default.
- W2051155563 hasRelatedWork W2027721780 @default.
- W2051155563 hasRelatedWork W2048471262 @default.
- W2051155563 hasRelatedWork W2264042629 @default.
- W2051155563 hasRelatedWork W2281428570 @default.
- W2051155563 hasRelatedWork W2335989971 @default.
- W2051155563 hasRelatedWork W2605325959 @default.
- W2051155563 hasRelatedWork W2606340465 @default.
- W2051155563 hasRelatedWork W2803453985 @default.
- W2051155563 hasVolume "501" @default.
- W2051155563 isParatext "false" @default.
- W2051155563 isRetracted "false" @default.
- W2051155563 magId "2051155563" @default.
- W2051155563 workType "article" @default.