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- W2051183769 abstract "The condensations of trimethyltriallylcyclotrisilazane, trimethyltribenzylcyclotrisilazane, dimethyldiphenyldibenzyldisilazane and methylphenylbenzylaminosilane in presence of catalytic amounts of KOH, Na and NaN(SiMe3)2 and their co-condensation with trimethyltriphenylcyclotrisilazane have been studied. Condensation of methylallyl- and methylbenzylcyclosilazane at temperatures above 300° results in hydrocarbon elimination and formation of solid glassy oligomers. Condensation with methylphenylcyclosilazanes occurs at 200–250° at a high rate with mainly propylene and toluene elimination. The radical chain mechanism for substitution of the organic groups on the silicon atom by silylamino or silazanyl groups, proposed earlier, has been confirmed." @default.
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- W2051183769 date "1985-01-01" @default.
- W2051183769 modified "2023-09-26" @default.
- W2051183769 title "Catalytic condensation of organosilazanes with allyl and benzyl groups on the silicon atom and their co-condensation with trimethyltriphenylcyclotrisilazane" @default.
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- W2051183769 doi "https://doi.org/10.1016/0032-3950(85)90350-8" @default.
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