Matches in SemOpenAlex for { <https://semopenalex.org/work/W2051199369> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2051199369 endingPage "388" @default.
- W2051199369 startingPage "382" @default.
- W2051199369 abstract "The electronic and physical properties of Cu2.33V4O11 were characterized by electrical resistivity, magnetic susceptibility and X-ray photoelectron spectroscopy (XPS) measurements and by tight-binding electronic band structure calculations. Attempts to prepare Cu2.33−xV4O11 outside its narrow homogeneity range led to a mixture of Cu2.33V4O11, CuVO3 and β-CuxV2O5. The magnetic susceptibility data show no evidence for a magnetic/structural transition around 300 K. The XPS spectra of Cu2.33V4O11 reveal the presence of mixed valence in both Cu and V. The [Cu+]/[Cu2+] ratio is estimated to be 1.11 from the Cu 2p3/2 peak areas, so [V4+]/[V5+]=0.56 by the charge balance. Our electronic structure calculations suggest that the oxidation state of the Cu ions is +2 in the channels of CuO4 tetrahedra, and +1 in the channels of linear CuO2 and trigonal planar CuO3 units. This predicts that [Cu+]/[Cu2+]=1.33 and [V4+]/[V5+]=0.50, in good agreement with those deduced from the XPS study." @default.
- W2051199369 created "2016-06-24" @default.
- W2051199369 creator A5022940710 @default.
- W2051199369 creator A5057960043 @default.
- W2051199369 creator A5064490013 @default.
- W2051199369 creator A5076524151 @default.
- W2051199369 creator A5083107018 @default.
- W2051199369 date "2002-07-01" @default.
- W2051199369 modified "2023-09-27" @default.
- W2051199369 title "Electrical Resistivity, Magnetic Susceptibility, X-Ray Photoelectron Spectroscopy, and Electronic Band Structure Studies of Cu2.33−xV4O11" @default.
- W2051199369 cites W1965389260 @default.
- W2051199369 cites W1968528677 @default.
- W2051199369 cites W1977763630 @default.
- W2051199369 cites W1977955686 @default.
- W2051199369 cites W1996734750 @default.
- W2051199369 cites W2006180049 @default.
- W2051199369 cites W2019826767 @default.
- W2051199369 cites W2070522761 @default.
- W2051199369 cites W2105680920 @default.
- W2051199369 cites W2323554077 @default.
- W2051199369 cites W2949454816 @default.
- W2051199369 cites W3173162390 @default.
- W2051199369 cites W7265026 @default.
- W2051199369 doi "https://doi.org/10.1006/jssc.2002.9609" @default.
- W2051199369 hasPublicationYear "2002" @default.
- W2051199369 type Work @default.
- W2051199369 sameAs 2051199369 @default.
- W2051199369 citedByCount "24" @default.
- W2051199369 countsByYear W20511993692012 @default.
- W2051199369 countsByYear W20511993692013 @default.
- W2051199369 countsByYear W20511993692017 @default.
- W2051199369 countsByYear W20511993692019 @default.
- W2051199369 countsByYear W20511993692021 @default.
- W2051199369 countsByYear W20511993692022 @default.
- W2051199369 crossrefType "journal-article" @default.
- W2051199369 hasAuthorship W2051199369A5022940710 @default.
- W2051199369 hasAuthorship W2051199369A5057960043 @default.
- W2051199369 hasAuthorship W2051199369A5064490013 @default.
- W2051199369 hasAuthorship W2051199369A5076524151 @default.
- W2051199369 hasAuthorship W2051199369A5083107018 @default.
- W2051199369 hasConcept C113196181 @default.
- W2051199369 hasConcept C121332964 @default.
- W2051199369 hasConcept C125469278 @default.
- W2051199369 hasConcept C145148216 @default.
- W2051199369 hasConcept C147597530 @default.
- W2051199369 hasConcept C16889073 @default.
- W2051199369 hasConcept C168900304 @default.
- W2051199369 hasConcept C175708663 @default.
- W2051199369 hasConcept C178790620 @default.
- W2051199369 hasConcept C185592680 @default.
- W2051199369 hasConcept C192562407 @default.
- W2051199369 hasConcept C26873012 @default.
- W2051199369 hasConcept C43617362 @default.
- W2051199369 hasConcept C46141821 @default.
- W2051199369 hasConcept C51286037 @default.
- W2051199369 hasConcept C62520636 @default.
- W2051199369 hasConcept C69990965 @default.
- W2051199369 hasConcept C8010536 @default.
- W2051199369 hasConcept C86025842 @default.
- W2051199369 hasConceptScore W2051199369C113196181 @default.
- W2051199369 hasConceptScore W2051199369C121332964 @default.
- W2051199369 hasConceptScore W2051199369C125469278 @default.
- W2051199369 hasConceptScore W2051199369C145148216 @default.
- W2051199369 hasConceptScore W2051199369C147597530 @default.
- W2051199369 hasConceptScore W2051199369C16889073 @default.
- W2051199369 hasConceptScore W2051199369C168900304 @default.
- W2051199369 hasConceptScore W2051199369C175708663 @default.
- W2051199369 hasConceptScore W2051199369C178790620 @default.
- W2051199369 hasConceptScore W2051199369C185592680 @default.
- W2051199369 hasConceptScore W2051199369C192562407 @default.
- W2051199369 hasConceptScore W2051199369C26873012 @default.
- W2051199369 hasConceptScore W2051199369C43617362 @default.
- W2051199369 hasConceptScore W2051199369C46141821 @default.
- W2051199369 hasConceptScore W2051199369C51286037 @default.
- W2051199369 hasConceptScore W2051199369C62520636 @default.
- W2051199369 hasConceptScore W2051199369C69990965 @default.
- W2051199369 hasConceptScore W2051199369C8010536 @default.
- W2051199369 hasConceptScore W2051199369C86025842 @default.
- W2051199369 hasIssue "2" @default.
- W2051199369 hasLocation W20511993691 @default.
- W2051199369 hasOpenAccess W2051199369 @default.
- W2051199369 hasPrimaryLocation W20511993691 @default.
- W2051199369 hasRelatedWork W1967961490 @default.
- W2051199369 hasRelatedWork W1979051620 @default.
- W2051199369 hasRelatedWork W1998639556 @default.
- W2051199369 hasRelatedWork W2011790752 @default.
- W2051199369 hasRelatedWork W2058043869 @default.
- W2051199369 hasRelatedWork W2058947355 @default.
- W2051199369 hasRelatedWork W2121649692 @default.
- W2051199369 hasRelatedWork W2465324054 @default.
- W2051199369 hasRelatedWork W2605687609 @default.
- W2051199369 hasRelatedWork W2979584463 @default.
- W2051199369 hasVolume "166" @default.
- W2051199369 isParatext "false" @default.
- W2051199369 isRetracted "false" @default.
- W2051199369 magId "2051199369" @default.
- W2051199369 workType "article" @default.