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- W2051201773 abstract "Dunkelgrune, kubische Kristalle (a = 21,446(10) A) von Bis(tetra-n-butyl-ammonium)-fluoro-phthalocyaninatohydrogenat-pentahydrat, (Bu4N)2[HFPc(2–)] · 5H2O, werden durch die Umsetzung von H2Pc(2–) mit uberschussigem (Bu4N)F · 3H2O bevorzugt in Dichlormethan oder Pyridin dargestellt. Die thermische Analyse zeigt zwei endotherme Gewichtsverluste, die bei T > 125°C der Abgabe des Kristallwassers und bei T > 180°C der Zersetzung des Komplexsalzes unter Bildung von H2Pc(2–) entsprechen. Die elektrochemischen (CV) und spektroskopischen Eigenschaften (UV-VIS-, IR-, Resonanz-Raman-, 1H-, 13C- und 19F-NMR-Spektren) werden beschrieben und mit denen von H2Pc(2–) verglichen.Synthesis und Properties of Bis(tetra-n-butylammonium)-fluoro-phthalocyaninato-hydrogenate-pentahydrateDarkgreen cubic crystals (a = 21.446(10) A) of bis(tetra-n-butylammonium)-fluoro-phthalocyaninatohydrogenate-pentahydrate, (Bu4N)2[HFPc(2–)] · 5H2O, are prepared by the reaction of H2Pc(2–) with excess (Bu4N)F · 3H2O preferably in dichloromethane or pyridine. The thermal analysis shows two endothermic losses in weight corresponding to the evaporation of crystal water at T > 125°C and the decomposition of the complex salt giving H2Pc(2–) at T > 180°C, respectively. The electrochemical (cv) and spectroscopical properties (uv-vis, i.r., resonance Raman, 1H, 13C, and 19F nmr spectra) are investigated and the characteristic differences with those of H2Pc(2–) are discussed." @default.
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- W2051201773 date "1991-05-01" @default.
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- W2051201773 title "Darstellung und Eigenschaften von Bis(tetra-n-butylammonium)-fluorophthalocyaninatohydrogenat-pentahydrat" @default.
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- W2051201773 doi "https://doi.org/10.1002/zaac.19915970116" @default.
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