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• W2051205443 startingPage "526" @default.
• W2051205443 abstract "The effects of metal particle size and support material on the kinetics of the COO2 and CONO reactions over Rh have been investigated. For the COO2 reaction in the CO-inhibition regime, both the specific rate and the apparent activation energy were found to be virtually independent of the Rh particle size, but moderately sensitive to the nature of the support material (with the low-temperature oxidation activity decreasing in the order Rh/α-Al2O3 > Rh/SiO2 > Rh/φ-Al2O3). The specific rate of the CONO reaction increased drastically with increasing Rh particle size; a 45-fold increase in specific rate was observed as the Rh particle size increased from 10 to 676 Å. However, support material had only a small effect on both the activity and selectivity of Rh for the CONO reaction." @default.
• W2051205443 created "2016-06-24" @default.
• W2051205443 creator A5002494133 @default.
• W2051205443 creator A5018430910 @default.
• W2051205443 date "1991-04-01" @default.
• W2051205443 modified "2023-10-14" @default.
• W2051205443 title "Influence of metal particle size and support on the catalytic properties of supported rhodium: CO$z.sbnd;O2 and CO$z.sbnd;NO reactions" @default.
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• W2051205443 doi "https://doi.org/10.1016/0021-9517(91)90310-z" @default.
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