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- W2051212214 abstract "Abstract The effect of nano-sized silica and γ-LiAlO2 on the electrochemical and interfacial properties of P(EO)20LiN(SO2CF2CF3)2–10 wt.% filler polymer electrolytes has been studied using linear sweep voltammetry, ac impedance and galvanostatic stripping/deposition on symmetric non-blocking cells. Non-symmetric cells were used to investigate the electrochemical stability window. The limiting current density of the P(EO)20LiBETI polymer electrolytes at 90 °C was found to decrease with the addition of nano-sized filler. The presence of silica caused higher interface resistance during storage in open circuit at 90 °C. For the galvanostatic Li stripping/deposition at 0.2 mA/cm2 at 90 °C, the silica containing electrolyte showed the highest initial overvoltage due to the high interface resistance. These results suggest that the presence of nano-size silica in solvent-free P(EO)20LiBETI polymer electrolytes results in no substantial improvement on the electrochemical and interfacial properties of the electrolytes at 90 °C." @default.
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- W2051212214 date "2004-04-01" @default.
- W2051212214 modified "2023-10-11" @default.
- W2051212214 title "Effect of fillers on the electrochemical and interfacial properties of PEO–LiN(SO2CF2CF3)2 polymer electrolytes" @default.
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- W2051212214 doi "https://doi.org/10.1016/j.electacta.2003.11.022" @default.
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