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- W2051212520 abstract "This paper describes a special method of laser-based deposition to synthesize palladium–ceramic composite membranes. Thin film Pd was deposited on a ceramic substrate by Nd-YAG laser irradiation of coating precursor PdCl2 on γ-alumina substrate. The parameters of the laser processing technique were optimized to synthesize metal–ceramic composite membranes. The physical and chemical characteristics of Pd coated γ-alumina membranes were studied and compared with various other alumina membranes referenced in the literature. Hydrogen permeation experiments were performed in a CO + CO2 + CH4 + H2 environment under typical catalytic steam gasifier exit conditions. The Pd–ceramic composite showed good mechanical and thermal stability and resulted in a hydrogen permeability flux of about 0.061 mol/m2 s. The activation energy of the Pd membrane was found to be 5.39 kJ/mol in a temperature range of 900–1300 °F." @default.
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- W2051212520 date "2006-11-01" @default.
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- W2051212520 title "Laser synthesis of palladium–alumina composite membranes for production of high purity hydrogen from gasification" @default.
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- W2051212520 doi "https://doi.org/10.1016/j.apsusc.2006.01.079" @default.
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